You can't boot Windows XP from a floppy disk the way you used to be able to with DOS. One handy way to easily boot XP is by using a USB flash drive. Here's how to make it work.
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Bart's PE Builder helps you build a 'BartPE' (Bart Preinstalled Environment) bootable Windows CD-Rom or DVD from the original Windows XP or Windows Server 2003 installation/setup CD, very suitable for PC maintenance tasks.